ELECTROSPRAY DEPOSITION OF THIN COPPER-INDIUM-DISELENIDE FILMS

In photovoltaics “thinness” generally is in reference to so-called “first generation” high-efficiency silicon cells, which are manufactured from bulk wafers hundreds of micrometers thick. In this process, two different precursor films are deposited separately on a substrate and a superstrate. Archived copy as title. Retrieved from ” https: Flexible substrates could eventually be used in this process. The property in which the module most obviously under-performed was a low V OC , which is characteristic of high defect density and high recombination velocities. However, all the modules that beat ISET’s module were coevaporated, a process which has manufacturing disadvantages and higher costs. Na is commonly supplied by the soda-lime glass substrate, but in processes that do not use this substrate the Na must be deliberately added.

In photovoltaics “thinness” generally is in reference to so-called “first generation” high-efficiency silicon cells, which are manufactured from bulk wafers hundreds of micrometers thick. Additionally, coevaporation is plagued by low material utilization deposition on chamber walls instead of the substrate, especially for selenium and expensive vacuum equipment. Na is commonly supplied by the soda-lime glass substrate, but in processes that do not use this substrate the Na must be deliberately added. Physica Status Solidi A. A surface orientation is observed in the best quality devices. Grid-connected photovoltaic power system List of photovoltaic power stations.

InCIGS efficiency was by far the highest compared with those achieved by other thin film technologies such as cadmium telluride photovoltaics CdTe or amorphous silicon a-Si. List of semiconductor materials Crystalline silicon c-Si Polycrystalline silicon multi-Si Monocrystalline silicon mono-Si Cadmium telluride Copper indium gallium selenide Amorphous silicon a-Si.

Thus, the buffer layer used is Cd-free, eliminating any environmental impact of Cd. Research is attempting to switch from dual-source precursors to single-source precursors. These interactions include formation of Cu-In-Ga intermetallic alloys, formation of intermediate metal-selenide binary compounds and phase separation of various stoichiometric CIGS compounds.

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This uses less energy than smelting large amounts of quartz sand in electric furnaces and growing large crystals, necessary for conventional silicon cells, and thus reduces its energy payback time significantly.

CIS layer deposition through electrospray process for solar cell fabrication

CIGS outperforms polysilicon at the cell level, however its module efficiency is still lower, due to a less mature upscaling. Retrieved 25 August A thin n-type buffer layer is added on top of the absorber.

They opened another production facility and continued to improve efficiency and yield. Boeing ‘s coevaporation process deposits bilayers of CIGS with different stoichiometries onto a heated substrate thn allows them to intermix.

Copper indium gallium selenide solar cells

List of countries by photovoltaics production. In the highly competitive PV industrypressure increased on CIGS manufacturersleading to the bankruptcy of several companies, as prices for conventional silicon cells declined rapidly in recent years. An alternative process is to co-evaporate copper, gallium, indium and selenium onto a heated substrate. Additionally, coevaporation is plagued by low material utilization deposition on chamber walls instead of the substrate, especially for selenium and expensive vacuum equipment.

Single-source precursor methods do not suffer from these drawbacks and should enable better control of film composition. A metal foil substrate is used as the working electrode in industrial processes. CIS films can be produced by electrospray deposition. Also, high growth temperatures raise the thermal copper-indium-diseleniide and costs.

However, as all of these technologies normally use high-temperature deposition techniques, the best performance normally comes from cells deposited on glass, even though advances in low-temperature deposition of CIGS cells have erased much of this performance difference. EPV films have a low defect concentration.

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The active CIGS-layer can be deposited in a polycrystalline form directly onto molybdenum Mo coated on a variety of several different wlectrospray such as glass sheets, steel bands and plastic foils made of polyimide. However, the first generations of products use higher temperature PVD methods and do not achieve full cost cutting potential. The sulfurization step appears to passivate the surface in a way similar to CdS in most other cells.

The advantages of this process include uniformity over large areas, non-vacuum or low-vacuum equipment and adaptability to roll-to-roll manufacturing. Like these materials, CIGS layers are thin enough to be flexible, allowing them to be deposited on flexible substrates.

The area of the interface increases with roughness while illuminated area remains constant, decreasing open circuit voltage V OC. Precursors can be deposited by electrodeposition. To reach the ideal bandgap for a single junction solar cell, 1.

During this step, called chalcogenization, complex interactions occur to form a chalcogenide. International Journal of Materials Research.

This page was last edited on 16 Februaryat When Se is supplied in the gas phase for example as H 2 Se or elemental Se at high temperatures, the Se becomes incorporated into the film by absorption and subsequent diffusion.

These semiconductors are especially attractive for solar applications because of their high optical absorption coefficients and versatile optical and electrical characteristics, which can in principle be manipulated and tuned for a specific need in a given device. Flexible substrates could eventually be used in this process.

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